Download e-book for iPad: Biomembranes - Part C: Biological Oxidations by Sidney Fleischer and Lester Packer (Eds.)

By Sidney Fleischer and Lester Packer (Eds.)

ISBN-10: 0121819523

ISBN-13: 9780121819521

The severely acclaimed laboratory common, Methods in Enzymology, is without doubt one of the such a lot hugely revered guides within the box of biochemistry. given that 1955, each one quantity has been eagerly awaited, usually consulted, and praised through researchers and reviewers alike. The sequence includes a lot fabric nonetheless appropriate at the present time - really a necessary booklet for researchers in all fields of existence sciences

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Ed. 11, 701 (1972). 33 H. Taube, J. Gen. Physiol. 49, 24 (1965). T. E. King, H. S. Mason, and M. " Univ. Park Press, Baltimore, Maryland, 1973. 34 S. Fallab, Z. Naturwiss. Med. Grundlagenforsch. 1,333 (1963). [1] MOLECULAR OXYGEN IN BIOLOGICAL OXIDATIONS 35 posed by the triplet state of 02 can be circumvented: (1) by complexation with a transition metal ion at the active site of the oxidase, since it is a spin-allowed process for a system with delocalized spins to react with organic compounds, producing singlet products (no unpaired electrons) if the number of unpaired electrons on the overall metal ion complex remains constant throughout the reaction.

Do ~. o . ~ " ~ ~ . -~ . ~ o~ 0o u. ~ ~'~ ~ . ~ ~ ~- • "~ =~ • o ~ - ~ <~'~:=~. < ~" ~" ~ - ' ~ [1] MOLECULAR OXYGEN IN BIOLOGICAL OXIDATIONS "6 e. r b- "6 z 0 Z 0 < ,~- ¢q ¢-4 < 0~ 0 Z r. < al < © O t- 0J a~ ¢q ee~ 33 34 GENERAL OVERVIEW [1] already known to be involved in some phases of oxygen metabolism: the dismutation of superoxide, the photosynthetic generation of molecular oxygen, and the peroxidatic oxidation of glutathione. Since copper proteins, iron proteins, and flavoproteins all occurred prior to the aerobic era of biology, 2~ it appears probable that the four predominant classes of prosthetic groups arose because of convergent evolution from precursors existing in the anaerobic era of life.

O ¢ ~ - ~ . ~:~ ~ 30 on~nght, o v r a w E w [1] ~0 ¢q t-" e~ • ~ ~ ¢'q e,~u ~ . / ~'~ ~ ~,. -. ~ -~I~ ~ ~ Ot ¢q r-- ~ "~ ~ ~ ,~ '~, 0 ~ ; ~ , . ~ . ~ ' ~ ' = ~ . 0 ~J - 0 _: ~ . ~ m ~ a . ,; ~ ¢~ o ~m ~. ~ • ~ ~_ ~: ~'0 ~ . ~ L~ ~ m ~ m . 'i= • ~, :I:l . o ~T=~. ,~ . [1] MOLECULAR OXYGEN 1N BIOLOGICAL OXIDATIONS eq d O 6.. ~'~ " ~" ~ ~- : ~ -~--~ 4 iu... O ~ ~~ • . o ~ -~ ~ = ~ , . - , .... -_~=. " i 1"-,I I['~1 ["',1 ~ " ~ 1 N 19,1 (~1 ~P-I I'~1 ¢~1 I N ~11"-,I t'~l ¢",11NI N £ 31 32 GENERAL OVERVIEW [1] xO Ox Ox xO t~ .

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Biomembranes - Part C: Biological Oxidations by Sidney Fleischer and Lester Packer (Eds.)


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